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Iron precatalysts with bulky tri(t‐butyl)cyclopentadienyl ligands for the dehydrocoupling of dimethylamine‐borane

Abstract:

In an attempt to prepare new Fe catalysts for the dehydrocoupling of amine‐boranes and to provide mechanistic insight, the paramagnetic FeII dimeric complex [Cp'FeI]2 (1) (Cp' = η5‐((1,2,4‐t‐Bu)3C5H2)) was used as a precursor to a series of cyclopentadienyl FeII and FeIII mononuclear species. The complexes prepared were [Cp'Fe(η6‐Tol)][Cp'FeI2] (2) (Tol = C6H5Me), [Cp'Fe(η6‐Tol)][BArF4] (3) (BArF4 = [B(C6H3(m‐CF3)2)4]‐), [N(n‐Bu)4][Cp'FeI2] (4), Cp'FeI2 (5), and [Cp'Fe(MeCN)3][BArF4] (6). Com...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1002/chem.201705316

Authors


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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Role:
Author
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Publisher:
Wiley‐VCH Verlag Publisher's website
Journal:
Chemistry - A European Journal Journal website
Volume:
24
Issue:
53
Pages:
14127-14136
Publication date:
2018-03-24
Acceptance date:
2018-03-08
DOI:
EISSN:
1521-3765
ISSN:
0947-6539
Pubs id:
pubs:830569
URN:
uri:a809de71-5d7a-4ada-a49c-8b40954ff8e9
UUID:
uuid:a809de71-5d7a-4ada-a49c-8b40954ff8e9
Local pid:
pubs:830569

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