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A NOMENCLATURE FOR LAMBDA-DOUBLET LEVELS IN ROTATING LINEAR-MOLECULES

Abstract:

It is proposed that the two Λ-doublet levels of linear molecules with nonzero electronic orbital angular momentum be labeled Λ(A′) and Λ(A″), e.g., Π(A′) and Π(A″) for Π states, etc., according to the following prescription: All series of levels in which the electronic wave function at high J is symmetric with reflection of the spatial coordinates of the electrons in the plane of rotation will be designated Λ(A′) for all values of J, and all those for which the electronic wave function is ant...

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Publication status:
Published

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Publisher copy:
10.1063/1.455121

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Journal:
JOURNAL OF CHEMICAL PHYSICS
Volume:
89
Issue:
4
Pages:
1749-1753
Publication date:
1988-08-15
DOI:
ISSN:
0021-9606
URN:
uuid:a7ee92b3-4638-4129-bd1a-ea3717842f61
Source identifiers:
43007
Local pid:
pubs:43007
Language:
English

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