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High-voltage metal-free disproportionation flow batteries based on 9,10-diphenylanthracene

Abstract:

Several metal-free, nonaqueous, disproportionation redox-flow-battery chemistries based on electrochemically active organic molecules are presented. The electrochemistry of 9,10-diphenylanthracene (DPA), a polycyclic aromatic compound, involves two reversible redox couples separated by more than 3 V, which are associated with electrochemical disproportionation of the neutral molecule. Nonaqueous solvents are investigated with the dual aims of realizing this high voltage in a battery cell and ...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1149/1945-7111/ab6a8d

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Institution:
University of Oxford
Division:
MPLS
Department:
Engineering Science
Sub department:
Engineering Science
Role:
Author
Publisher:
IOP Science Publisher's website
Journal:
Journal of The Electrochemical Society Journal website
Volume:
167
Issue:
7
Pages:
070517-070517
Publication date:
2020-01-29
Acceptance date:
2020-01-06
DOI:
EISSN:
1945-7111
Language:
English
Pubs id:
1085708
Local pid:
pubs:1085708
Deposit date:
2020-02-07

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