Journal article
A surface and catalytic study of heterogenised Os3(CO) 12 species in MCM-41 structures
- Abstract:
-
Immobilised Os species prepared via chemical vapour deposition (CVD) of Os3(CO)12 onto MCM-41 are active and selective catalysts for the dihydroxylation of trans-stilbene in acetone and water, using N-methylmorpholine N-oxide as the oxidant. A detailed temperature programmed decomposition study of the solids enables to identify the active sites as Osx(CO)y surface species. The initial loading of the MCM-41 with the trinuclear precursor, as well as the temperature of the post-synthesis oxidisi...
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- Publisher copy:
- 10.1016/S0926-860X(03)00372-7
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Bibliographic Details
- Journal:
- Applied Catalysis A: General
- Volume:
- 252
- Issue:
- 1
- Pages:
- 37-49
- Publication date:
- 2003-10-08
- DOI:
- ISSN:
-
0926-860X
- URN:
-
uuid:a770b73f-9370-4e8f-8f3d-2a7864cd2c75
- Source identifiers:
-
180228
- Local pid:
- pubs:180228
Item Description
- Language:
- English
- Keywords:
Terms of use
- Copyright date:
- 2003
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