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A surface and catalytic study of heterogenised Os3(CO) 12 species in MCM-41 structures

Abstract:

Immobilised Os species prepared via chemical vapour deposition (CVD) of Os3(CO)12 onto MCM-41 are active and selective catalysts for the dihydroxylation of trans-stilbene in acetone and water, using N-methylmorpholine N-oxide as the oxidant. A detailed temperature programmed decomposition study of the solids enables to identify the active sites as Osx(CO)y surface species. The initial loading of the MCM-41 with the trinuclear precursor, as well as the temperature of the post-synthesis oxidisi...

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Authors


Paraskevas, I More by this author
Journal:
Applied Catalysis A: General
Volume:
252
Issue:
1
Pages:
37-49
Publication date:
2003-10-08
DOI:
ISSN:
0926-860X
URN:
uuid:a770b73f-9370-4e8f-8f3d-2a7864cd2c75
Source identifiers:
180228
Local pid:
pubs:180228

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