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Thesis

Topochemical fluorination of some Ruddlesden-Popper phases

Abstract:

This thesis describes the synthesis and the characterization of some n = 2 Ruddlesden-Popper oxide phases (A3B2O7; A = La, Y, Sr or Ca; B = Cr, Ni or Mn) and their topochemically fluorinated phases.

La2SrCr2O7 adopts an A2/a (a-a-c-/a-a-c-) distorted structure with antiferromagnetic order below TN ~ 260 K. DFT calculations performed on La2SrCr2...

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Ronghuan Zhang More by this author

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Role:
Supervisor
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford

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