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PHOTOELECTROCHEMICAL ELECTRON-SPIN-RESONANCE .4. THE PHOTO-ECE REACTION AND THE REDUCTION OF 1-HALOGENOANTHRAQUINONES

Abstract:: The reduction of 1-bromoanthraquinone in acetonitrile solvent in the presence of tetrabutylammonium perchlorate, at irradiated (565 nm) gold electrodes is shown to produce the radical anion of anthraquinone. A combination of photoelectrochemical hydrodynamic voltammetry, in situ electrochemical ESR and preparative experiments are used to deduce that the mechanism is a 'photo-ECE' reaction, in which the first electron transfer produces the radical anion of 1-bromoanthraquinone. On irradiation,...
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APA Style

Compton, R., Coles, B., Pilkington, M., & Bethell, D. (1990). PHOTOELECTROCHEMICAL ELECTRON-SPIN-RESONANCE .4. THE PHOTO-ECE REACTION AND THE REDUCTION OF 1-HALOGENOANTHRAQUINONES. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 86(4), 663–670.

MLA Style

Compton, R., et al. “PHOTOELECTROCHEMICAL ELECTRON-SPIN-RESONANCE .4. THE PHOTO-ECE REACTION AND THE REDUCTION OF 1-HALOGENOANTHRAQUINONES.” JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, vol. 86, no. 4, 1990, pp. 663–70.

Chicago Style

Compton, R, B Coles, M Pilkington, and D Bethell. 1990. “PHOTOELECTROCHEMICAL ELECTRON-SPIN-RESONANCE .4. THE PHOTO-ECE REACTION AND THE REDUCTION OF 1-HALOGENOANTHRAQUINONES.” JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS 86 (4): 663–70.
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Publisher copy:: 10.1039/ft9908600663

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+ Compton, R More by this author

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+ Coles, B More by this author

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+ Pilkington, M More by this author

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+ Bethell, D More by this author

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Bibliographic Details

Journal:: JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS
Volume:: 86
Issue:: 4
Pages:: 663-670
Publication date:: 1990-02-21
DOI:: 10.1039/ft9908600663
EISSN:: 1364-5455
ISSN:: 0956-5000

Item Description

Language:: English
Pubs id:: pubs:43280
UUID:: uuid:a6e463bb-1d84-464f-95f3-caa0056bfc87
Local pid:: pubs:43280
Source identifiers:: 43280
Deposit date:: 2012-12-19

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Copyright date:: 1990

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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