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A NOVEL ONE-POT SYNTHESIS OF HOMOCHIRAL (R)-(-) AND (S)-(+)-FE(CO)(ETA(5)-C5H5)(PPH(3))COCH3

Abstract:
Treatment of the salt [Fe(CO)2(η5-C 5H5)(PPh3)]Br with potassium L-mentholate followed by lithium bromide and methyllithium generates, after work-up and crystallisation, homochiral (S)-(+)-[Fe(CO)(η5-C 5H5)(PPh3)COCH3] in ≥ 30% yield.
Publication status:
Published

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Publisher copy:
10.1039/p19940002369

Authors


COSTELLO, J More by this author
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
Issue:
17
Pages:
2369-2372
Publication date:
1994-09-07
DOI:
EISSN:
1364-5463
ISSN:
0300-922X
URN:
uuid:a6d2f32f-be1e-4946-a85d-142f9936a379
Source identifiers:
110861
Local pid:
pubs:110861
Language:
English

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