- Abstract:
- Treatment of the salt [Fe(CO)2(η5-C 5H5)(PPh3)]Br with potassium L-mentholate followed by lithium bromide and methyllithium generates, after work-up and crystallisation, homochiral (S)-(+)-[Fe(CO)(η5-C 5H5)(PPh3)COCH3] in ≥ 30% yield.
- Publication status:
- Published
- Publisher copy:
- 10.1039/p19940002369
-
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- Journal:
- JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
- Issue:
- 17
- Pages:
- 2369-2372
- Publication date:
- 1994-09-07
- DOI:
- EISSN:
-
1364-5463
- ISSN:
-
0300-922X
- URN:
-
uuid:a6d2f32f-be1e-4946-a85d-142f9936a379
- Source identifiers:
-
110861
- Local pid:
- pubs:110861
- Language:
- English
- Copyright date:
- 1994
Journal article
A NOVEL ONE-POT SYNTHESIS OF HOMOCHIRAL (R)-(-) AND (S)-(+)-FE(CO)(ETA(5)-C5H5)(PPH(3))COCH3
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