Journal article
1,2-Diphosphinobenzene as a synthon for the 1,2,3-triphospha- and 2-arsa-1,3-diphosphaindenyl anions and a stable organo derivative of the P8 unit of Hittorf's phosphorus.
- Abstract:
-
The electronic structure of the 1,2,3-triphosphaindenyl ligand suggests that it should exhibit enhanced pi-acceptor properties when compared to the eta(5)-indenyl system; this insight encouraged us to develop a simple synthetic pathway from 1,2-diphosphinobenzene to the 1,2,3-C(6)H(4)P(3) and 2-As-1,3-C(6)H(4)P(2) anions, both of which have been structurally characterised by X-ray crystallography; as a bonus from these studies we also obtained the first structurally characterised organo deriv...
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- Publication status:
- Published
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Bibliographic Details
- Journal:
- Chemical Communications
- Issue:
- 7
- Pages:
- 856-858
- Publication date:
- 2008-02-01
- DOI:
- EISSN:
-
1364-548X
- ISSN:
-
1359-7345
Item Description
- Language:
- English
- Pubs id:
-
pubs:50415
- UUID:
-
uuid:a6c0407a-fb15-4bd9-9cc1-20dcf648e873
- Local pid:
- pubs:50415
- Source identifiers:
-
50415
- Deposit date:
- 2012-12-19
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- Copyright date:
- 2008
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