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Microwave activation of electrochemical processes at microelectrodes

Abstract:
Electrochemical experiments at platinum microdisc electrodes are shown to be possible in an environment of intense microwave radiation and a considerable current enhancement observed for the ferrocyanide/ferricyanide redox couple in aqueous 1 M KCl is shown to be Faradaic in nature consistent with a rapid heating effect causing the temperature in the liquid phase at the electrode/solution interface to locally superheat.
Publication status:
Published

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Publisher copy:
10.1039/a806511j

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
CHEMICAL COMMUNICATIONS
Issue:
23
Pages:
2595-2596
Publication date:
1998-12-07
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Source identifiers:
36778
Language:
English
Pubs id:
pubs:36778
UUID:
uuid:a6b17427-a465-44ad-9e57-48cf39b51cbe
Local pid:
pubs:36778
Deposit date:
2012-12-19

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