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Ordering, flexibility and frustration in arrays of porphyrin nanorings.

Abstract:

The regular packing of atoms, molecules and nanoparticles provides the basis for the understanding of structural order within condensed phases of matter. Typically the constituent particles are considered to be rigid with a fixed shape. Here we show, through a combined experimental and numerical study of the adsorption of cyclic porphyrin polymers, nanorings, on a graphite surface, that flexible molecules can exhibit a rich and complex packing behaviour. Depending on the number of porphyrin s...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1038/s41467-019-11009-y

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
ORCID:
0000-0002-1801-8132
Publisher:
Nature Research Publisher's website
Journal:
Nature Communications Journal website
Volume:
10
Article number:
2932
Publication date:
2019-07-03
Acceptance date:
2019-06-13
DOI:
EISSN:
2041-1723
Pmid:
31270343
Language:
English
Keywords:
Pubs id:
pubs:1030607
UUID:
uuid:a6af2248-bc8b-4dcc-ac4a-df3bf094782c
Local pid:
pubs:1030607
Source identifiers:
1030607
Deposit date:
2019-08-01

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