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Comparison of new microemulsion prepared "Pt-in-ceria" catalyst with conventional "Pt-on-ceria" catalyst for water-gas shift reaction

Abstract:
New "Pt-in-CeO2 catalyst prepared by microemulsion method is shown to give higher activity for a water-gas shift reaction but with no formation of CH4, the side product from hydrogenation of carbon oxides using a hydrogen-rich reformate as compared to conventional "Pt-on-CeO2" catalysts. Detailed characterization by DRIFT analysis and temperature programmed reduction presented in this work clearly suggest the ceria coverage on Pt inhibits the metal from forming a strong CO adsorption. © 2006 American Chemical Society.

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Publisher copy:
10.1021/jp061083u
Journal:
Journal of Physical Chemistry B
Volume:
110
Issue:
17
Pages:
8540-8543
Publication date:
2006-05-04
DOI:
ISSN:
1520-6106
Language:
English
Pubs id:
pubs:180209
UUID:
uuid:a69ba4fc-3e4a-4c8c-885c-8ddee2d189f8
Local pid:
pubs:180209
Source identifiers:
180209
Deposit date:
2012-12-19

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