Journal article
Synthesis and characterisation of some new boron compounds containing the 2,4,6-(CF3)(3)C6H2 (fluoromes = Ar), 2,6-(CF3)(2)C6H3 (fluoroxyl = Ar '), or 2,4-(CF3)(2)C6H3 (Ar '') ligands
- Abstract:
-
Several new boron compounds containing the 2,4,6- (CF3)3C6H2 (fluoromes = Ar), 2,6-(CF3)2C6H3 (fluoroxyl = Ar′) or 2,4-(CF3)2C6H3 (Ar″) ligands have been synthesised from reactions of ArLi, Ar′Li or Ar″Li with BCl3, and characterised by 19F and 11B NMR spectroscopy. Chlorine/fluorine exchanges are evident in these reactions. The crystal and molecular structures of Ar2BF, Ar″3B, Ar2B(OH), Ar′B(OH)2 and Mes2BF (Mes = 2,4,6-Me3C6H2) have been determined by single crystal X-ray diffraction. Ar″3B...
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- Publication status:
- Published
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- Publisher copy:
- 10.1039/b309820f
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Bibliographic Details
- Journal:
- DALTON TRANSACTIONS
- Issue:
- 23
- Pages:
- 4395-4405
- Publication date:
- 2003-01-01
- DOI:
- ISSN:
-
1477-9226
- Source identifiers:
-
117221
Item Description
- Language:
- English
- Pubs id:
-
pubs:117221
- UUID:
-
uuid:a6605fb0-f83e-4437-874b-7521d4fef989
- Local pid:
- pubs:117221
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2003
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