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Synthesis and characterisation of some new boron compounds containing the 2,4,6-(CF3)(3)C6H2 (fluoromes = Ar), 2,6-(CF3)(2)C6H3 (fluoroxyl = Ar '), or 2,4-(CF3)(2)C6H3 (Ar '') ligands

Abstract:

Several new boron compounds containing the 2,4,6- (CF3)3C6H2 (fluoromes = Ar), 2,6-(CF3)2C6H3 (fluoroxyl = Ar′) or 2,4-(CF3)2C6H3 (Ar″) ligands have been synthesised from reactions of ArLi, Ar′Li or Ar″Li with BCl3, and characterised by 19F and 11B NMR spectroscopy. Chlorine/fluorine exchanges are evident in these reactions. The crystal and molecular structures of Ar2BF, Ar″3B, Ar2B(OH), Ar′B(OH)2 and Mes2BF (Mes = 2,4,6-Me3C6H2) have been determined by single crystal X-ray diffraction. Ar″3B...

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Publication status:
Published

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Publisher copy:
10.1039/b309820f

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Journal:
DALTON TRANSACTIONS
Issue:
23
Pages:
4395-4405
Publication date:
2003-01-01
DOI:
ISSN:
1477-9226
URN:
uuid:a6605fb0-f83e-4437-874b-7521d4fef989
Source identifiers:
117221
Local pid:
pubs:117221
Language:
English

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