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Tris(2-methoxyphenyl) phosphite complexes of platinum(II): The cis preference of triaryl phosphite ligands and the effect of oxidation state on metal phosphite bonding

Abstract:

The complexes cis-[PtX2{P(OC6H4OMe-2)3} 2] (X = Cl, Br or I) have been prepared by treatment of the corresponding [PtX2(cod)] (cod = cycloocta-1,5-diene) with P(OC6H4OMe-2)3. That with X = Cl reacted with 1 or 2 equivalents of SnCl2 to give cis-[PtCl(SnCl3){P(OC6H4OMe-2) 3}2] or trans-[Pt(SnCl3)2{P(OC6H4OMe-2) 3}2]. The unstable hydride trans-[PtH(Cl){P(OC6H4OMe-2)3}2] was detected when cis-[PtCl2{P(OC6H4OMe-2)3} 2] was treated with NaBH4 or [Pt{P(OC6H4OMe-2)3}3] with HCl. The organoplatinum ...

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Publication status:
Published

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Publisher copy:
10.1039/dt9960001069

Authors


Crispini, A More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry
Pringle, PG More by this author
Wheatcroft, JR More by this author
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue:
6
Pages:
1069-1076
Publication date:
1996-03-21
DOI:
EISSN:
1364-5447
ISSN:
0300-9246
URN:
uuid:a633f9f2-5386-4755-ae5f-58297577a3ff
Source identifiers:
327108
Local pid:
pubs:327108
Language:
English

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