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Hydroacylation of Alkenes, Alkynes, and Allenes

Abstract:

The addition of an aldehyde across the C. C multiple bond of an alkene, an alkyne, or an allene delivers a synthetically useful ketone-containing product. The most widely used versions of these transformations are promoted by transition metal complexes, with rhodium catalysts dominating. Intramolecular reactions to deliver cyclopentanones are well developed, and larger-ring ketones can also be prepared provided appropriate substrates are employed. The efficiency of intermolecular reactions is...

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Authors


Willis, MC More by this author
Publisher:
Elsevier Ltd.
Volume:
4
Pages:
961-994
Host title:
Comprehensive Organic Synthesis: Second Edition
Publication date:
2014-02-05
DOI:
URN:
uuid:a61f8075-47fa-4be0-a214-680ed83ebb91
Source identifiers:
476803
Local pid:
pubs:476803
ISBN:
9780080977430

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