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Functionalized bis(thiosemicarbazonato) complexes of zinc and copper: synthetic platforms toward site-specific radiopharmaceuticals.

Abstract:

Two new types of unsymmetrical bis(thiosemicarbazone) proligands and their neutral zinc(II) and copper(II) complexes have been synthesized. These bifunctional ligands both chelate the metal ions and provide pendent amino groups that can be readily functionalized with biologically active molecules. Functionalization has been demonstrated by the synthesis of three water-soluble glucose conjugates of the new zinc(II) bis(thiosemicarbazonato) complexes, and their copper(II) analogues have been pr...

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Publication status:
Published

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Publisher copy:
10.1021/ic0615628

Authors


Holland, JP More by this author
Aigbirhio, FI More by this author
Bonnitcha, PD More by this author
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Journal:
Inorganic chemistry
Volume:
46
Issue:
2
Pages:
465-485
Publication date:
2007-01-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:a60b75be-d5c2-4050-8503-251a93872822
Source identifiers:
33747
Local pid:
pubs:33747
Language:
English

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