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Dehydrogenation of cyclic thioethers bound to a [Rh(diphosphine)]+ fragment.

Abstract:
The metal-promoted dehydrogenation of cyclic thioethers S(C(5)H(9))(R) (R = C(5)H(9), Ph) to give the corresponding cycloalkenes, S(C(5)H(7))(R), using the [Rh{Ph(2)P(CH(2))(3)PPh(2)}](+) fragment is reported.
Publication status:
Published

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Publisher copy:
10.1039/c1dt10503e

Authors


Dallanegra, R More by this author
Pilgrim, BS More by this author
Chaplin, AB More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
Dalton transactions (Cambridge, England : 2003)
Volume:
40
Issue:
25
Pages:
6626-6628
Publication date:
2011-07-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:a5ef5077-31a1-4a7a-aa52-2d92edd071c6
Source identifiers:
142231
Local pid:
pubs:142231
Language:
English

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