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A Study of the Na/Na+ Redox Couple in Some Room Temperature Ionic Liquids

Abstract:

Cyclic voltammetry experiments were conducted using solutions of Na + ions in 12 different ionic liquids (RTILs) on a nickel microelectrode in order to observe the deposition and stripping of metallic sodium. In most of the liquids the potential window was insufficient to observe the formation and removal of bulk sodium, despite the enlargement of some potential windows in the presence of sodium. However, in the ionic liquids N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([C...

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Publication status:
Published

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Publisher copy:
10.1021/jp911862m

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
JOURNAL OF PHYSICAL CHEMISTRY C
Volume:
114
Issue:
8
Pages:
3618-3626
Publication date:
2010-03-04
DOI:
EISSN:
1932-7455
ISSN:
1932-7447
URN:
uuid:a52e3939-54b1-44f5-bbdc-345e8a94205c
Source identifiers:
50339
Local pid:
pubs:50339
Language:
English

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