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Quantifying the apparent 'Catalytic' effect of porous electrode surfaces

Abstract:

The voltammetry of porous electroactive surfaces is investigated by simulation. The surface is modelled as a solid block penetrated by a regularly distributed array of cylindrical pores. The effect of the voltage scan rate and the geometry (in terms of pore depth, radius, and inter-pore separation) of the porous surface on the voltammetry is examined for both fully reversible and fully irreversible electrode kinetics. In the latter case, it is demonstrated that when the pores are relatively s...

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Publication status:
Published

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Publisher copy:
10.1016/j.jelechem.2014.04.009

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Publisher:
Elsevier
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY More from this journal
Volume:
724
Pages:
43-47
Publication date:
2014-06-15
DOI:
ISSN:
1572-6657
Language:
English
Keywords:
Pubs id:
pubs:466892
UUID:
uuid:a48e8a59-4ecd-4da7-94fa-1f599809cbe9
Local pid:
pubs:466892
Source identifiers:
466892
Deposit date:
2014-07-04

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