- Abstract:
-
Chiral ion-pairs are playing an increasingly important role in asymmetric catalysis. In order to understand the source of molecular recognition, a simple model system based on a BINAP-Rh(dialkene) cation and a BINOL borate anion was studied for both diastereomeric forms. It was discovered that one of these was energetically preferred and methods for quantifying the difference were devised using 31P NMR. The effect was general over a series of bis-binaphthyl borate anions, and required cyclooc...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1039/c3sc51096d
-
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- Journal:
- CHEMICAL SCIENCE
- Volume:
- 4
- Issue:
- 8
- Pages:
- 3140-3147
- Publication date:
- 2013-01-01
- DOI:
- EISSN:
-
2041-6539
- ISSN:
-
2041-6520
- URN:
-
uuid:a3e2a3a9-c60f-4067-a46c-39b6438f5a99
- Source identifiers:
-
414837
- Local pid:
- pubs:414837
- Language:
- English
- Copyright date:
- 2013
Journal article
Chiral recognition in contact ion-pairs; observation, characterization and analysis
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