Journal article
Chiral recognition in contact ion-pairs; observation, characterization and analysis
- Abstract:
-
Chiral ion-pairs are playing an increasingly important role in asymmetric catalysis. In order to understand the source of molecular recognition, a simple model system based on a BINAP-Rh(dialkene) cation and a BINOL borate anion was studied for both diastereomeric forms. It was discovered that one of these was energetically preferred and methods for quantifying the difference were devised using 31P NMR. The effect was general over a series of bis-binaphthyl borate anions, and required cyclooc...
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- Publication status:
- Published
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- Publisher copy:
- 10.1039/c3sc51096d
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Authors
Bibliographic Details
- Journal:
- CHEMICAL SCIENCE
- Volume:
- 4
- Issue:
- 8
- Pages:
- 3140-3147
- Publication date:
- 2013-01-01
- DOI:
- EISSN:
-
2041-6539
- ISSN:
-
2041-6520
- Source identifiers:
-
414837
Item Description
- Language:
- English
- Pubs id:
-
pubs:414837
- UUID:
-
uuid:a3e2a3a9-c60f-4067-a46c-39b6438f5a99
- Local pid:
- pubs:414837
- Deposit date:
- 2013-11-17
Terms of use
- Copyright date:
- 2013
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