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Sr11Ge4N6: a new nitride composed of [GeN2Sr7]4+ antiperovskite-type slabs and [Sr4Ge]4+ layers, separated by sheets of bent [Ge(II)N2]4- ions.

Abstract:
The layered nitride Sr11Ge4N6 contains Ge4- Zintl anions in both [Sr4Ge]4+ layers and [GeN2Sr7]4+ antiperovskite-type slabs which are separated by sheets of bent [Ge(II)N2]4- ions; the observed range of formal germanium oxidation states in nitrides thus extends between +4 and -4.
Publication status:
Published

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Publisher copy:
10.1039/b413534b

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
Chemical communications (Cambridge, England)
Issue:
6
Pages:
728-730
Publication date:
2005-02-05
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
URN:
uuid:a3b80b7f-a560-442f-b21f-85cea18e667b
Source identifiers:
32973
Local pid:
pubs:32973
Language:
English

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