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An unsaturated peptidomimetic assembly derived from a carbohydrate.

Abstract:

A strategy has been established for the synthesis of peptidomimetics derived from unsaturated carbohydrates, and exemplified by the use of methyl 2,6-anhydro-7-azido-3,7-deoxy-4,5-O-isopropylidene-D-lyxo-hept-2-enonate 9 as a dipeptide 'monomer' which can be elaborated from either end. Selective reduction of 9 gives a protected pseudodipeptide ester suitable for use as an amino component, and saponification gives an azido acid suitable for use as a carboxyl component. The 'dimer' product of c...

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Publication status:
Published

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Publisher copy:
10.1002/psc.488

Authors


Claridge, TD More by this author
Johnson, SW More by this author
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Journal:
Journal of peptide science : an official publication of the European Peptide Society
Volume:
10
Issue:
1
Pages:
1-7
Publication date:
2004-01-05
DOI:
EISSN:
1099-1387
ISSN:
1075-2617
URN:
uuid:a376cbaa-191f-4e5f-89da-c57c9f00f2fa
Source identifiers:
38920
Local pid:
pubs:38920

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