Journal article
Competing Magnetic Structures and the Evolution of Copper Ion/Vacancy Ordering with Composition in the Manganite Oxide Chalcogenides Sr2MnO2Cu1.5(S1-xSex)(2)
- Abstract:
-
The series Sr 2MnO 2Cu 1.5(S 1-xSe x) 2 (0 ≤ x ≤ 1) contains mixed-valent Mn ions (Mn 2+/Mn 3+) in MnO 2 sheets which are separated by copper-deficient antifluorite-type Cu 2-δCh 2 layers with δ ∼ 0.5. The compounds crystallize in the structure type first described for Sr 2Mn 3Sb 2O 2 and are described in the I4/mmm space group at ambient temperatures. Below about 250 K, ordering between Cu + ions and tetrahedral vacancies occurs which is long-range and close to complete in the sulfide-contai...
Expand abstract
- Publication status:
- Published
Actions
Access Document
- Publisher copy:
- 10.1021/cm301486v
Why is the content I wish to access not available via ORA?
Bibliographic data (the information relating to research outputs) and full-text items (e.g. articles, theses, reports, etc.) arrive in ORA from several different sources. Unfortunately we are not able to make available the full-text for every research output.
Please contact the ORA team (
) if you have queries regarding unavailable content OR if you are aware of a full-text copy we can make available.
) if you have queries regarding unavailable content OR if you are aware of a full-text copy we can make available.
Content may be unavailable for the following four reasons
-
Version unsuitable
-
We have not obtained a suitable full-text for a given research output. See this page for more information.
-
Recently completed
-
Sometimes content is held in ORA but is unavailable for a fixed period of time to comply with the policies and wishes of rights holders.
-
Permissions
-
All content made available in ORA should comply with relevant rights, such as copyright. See this page for more information.
-
Clearance
-
Some thesis volumes scanned as part of the digitisation scheme funded by Dr Leonard Polonsky are currently unavailable due to sensitive material or uncleared third-party copyright content. We are attempting to contact authors whose theses are affected.
Alternative access to the full-text
You may be able to access the full-text directly from the publisher's website using the 'Publisher Copy' link in the 'Links & Downloads' box from a research output's ORA record page. This method may require an institutional or individual subscription to the journal/resource.
Authors
Bibliographic Details
- Journal:
- CHEMISTRY OF MATERIALS
- Volume:
- 24
- Issue:
- 14
- Pages:
- 2802-2816
- Publication date:
- 2012-07-24
- DOI:
- EISSN:
-
1520-5002
- ISSN:
-
0897-4756
- Source identifiers:
-
348810
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:348810
- UUID:
-
uuid:a313ca8b-8afa-47e7-8a74-3ff32587c84f
- Local pid:
- pubs:348810
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2012
If you are the owner of this record, you can report an update to it here: Report update to this record