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Voltammetry of surface-bound species: Proton-coupled electrochemical reduction

Abstract:

We consider the one electron, one proton and also the two electron, two proton reductions of surface-bound species. Two mechanisms of reaction are considered: stepwise and concerted. The voltammetry is modelled under three regimes of proton transport: infinitely fast (fully buffered solution), infinitely slow (infinitely high surface coverage of electrode) and the intermediate case of a finite rate of diffusional mass transport to electrode surface. The types of voltammograms observed in each...

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Publication status:
Published

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Publisher copy:
10.1016/j.jelechem.2010.11.024

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY More from this journal
Volume:
651
Issue:
2
Pages:
118-130
Publication date:
2011-02-01
DOI:
ISSN:
1572-6657
Language:
English
Keywords:
Pubs id:
pubs:120382
UUID:
uuid:a25ea166-dce8-40ac-ba59-80dc2875ecc4
Local pid:
pubs:120382
Source identifiers:
120382
Deposit date:
2012-12-19

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