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A NOVEL ELECTRODE FOR ELECTROCHEMICAL ELECTRON-SPIN-RESONANCE AND ITS APPLICATION TO MODIFIED ELECTRODES

Abstract:

A tube electrode consisting of an incomplete annulus can be placed in the cavity of an ESR spectrometer without detuning the cavity. The ESR signals from the radical cation of N,N,N prime ,N prime -tetramethylphenylenediamine, produced by oxidation on a semiannular electrode at the center of the cavity, are shown to obey the solution to the convective diffusion equation, describing the transport of the radicals away from the electrode. Radicals in the coats of modified electrodes may be studi...

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Publication status:
Published

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Publisher copy:
10.1021/ja00315a001

Authors


COMPTON, R More by this author
Journal:
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume:
106
Issue:
3
Pages:
469-473
Publication date:
1984
DOI:
ISSN:
0002-7863
URN:
uuid:a1a047a1-7466-420f-906b-6228f132699d
Source identifiers:
52933
Local pid:
pubs:52933
Language:
English

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