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A MICROSCOPIC MODEL OF ELECTRON-TRANSFER AT ELECTROACTIVE SITES OF MOLECULAR DIMENSIONS FOR REDUCTION OF CYTOCHROME-C AT BASAL-PLANE AND EDGE-PLANE GRAPHITE-ELECTRODES

Abstract:: A microscopic model of electron transfer, which assumes that electron transfer occurs only after radial diffusion to oxygen-functionalized sites of molecular dimension in size, has been developed to explain the electrochemical reduction of horse heart cytochrome c at graphite electrodes. By use of this model, the conclusion is reached that the rate of electron transfer is greater than 1 cm s-1 at both basal- and edge-plan graphite electrodes and silanized or "aged" graphite electrodes. Accord...
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APA Style

Armstrong, F., Bond, A., Hill, H., Psalti, I., & Zoski, C. (1989). A MICROSCOPIC MODEL OF ELECTRON-TRANSFER AT ELECTROACTIVE SITES OF MOLECULAR DIMENSIONS FOR REDUCTION OF CYTOCHROME-C AT BASAL-PLANE AND EDGE-PLANE GRAPHITE-ELECTRODES. JOURNAL OF PHYSICAL CHEMISTRY, 93(17), 6485–6493.

MLA Style

Armstrong, F., et al. “A MICROSCOPIC MODEL OF ELECTRON-TRANSFER AT ELECTROACTIVE SITES OF MOLECULAR DIMENSIONS FOR REDUCTION OF CYTOCHROME-C AT BASAL-PLANE AND EDGE-PLANE GRAPHITE-ELECTRODES.” JOURNAL OF PHYSICAL CHEMISTRY, vol. 93, no. 17, 1989, pp. 6485–93.

Chicago Style

Armstrong, F, A Bond, H Hill, I Psalti, and C Zoski. 1989. “A MICROSCOPIC MODEL OF ELECTRON-TRANSFER AT ELECTROACTIVE SITES OF MOLECULAR DIMENSIONS FOR REDUCTION OF CYTOCHROME-C AT BASAL-PLANE AND EDGE-PLANE GRAPHITE-ELECTRODES.” JOURNAL OF PHYSICAL CHEMISTRY 93 (17): 6485–93.
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Publisher copy:: 10.1021/j100354a041

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+ Armstrong, F More by this author

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+ Bond, A More by this author

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+ Hill, H More by this author

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+ Psalti, I More by this author

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+ Zoski, C More by this author

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Bibliographic Details

Journal:: JOURNAL OF PHYSICAL CHEMISTRY
Volume:: 93
Issue:: 17
Pages:: 6485-6493
Publication date:: 1989-08-24
DOI:: 10.1021/j100354a041
EISSN:: 1541-5740
ISSN:: 0022-3654

Item Description

Language:: English
Pubs id:: pubs:43032
UUID:: uuid:a0c1ca0d-d114-4cff-a0da-3557d6f50f33
Local pid:: pubs:43032
Source identifiers:: 43032
Deposit date:: 2013-11-17

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Copyright date:: 1989

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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