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Heptaphosphide cluster anions bearing group 14 element amide functionalities.

Abstract:

Reactions of the protonated heptaphosphide dianion, [HP7](2-), with one equivalent of E[N(SiMe3)2]2 (E = Ge, Sn, Pb) give rise to novel derivatized cluster anions [P7EN(SiMe3)2](2-) (E = Ge (1), Sn (2) and Pb (3)). All three species were characterized by multi-element solution-phase NMR spectroscopy and electrospray ionization mass spectrometry. In addition, 1 and 2 were structurally authenticated by means of single crystal X-ray diffraction in [K(18-crown-6)]2[P7EN(SiMe3)2]·2py. Interestingl...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/c5dt02380g

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Paterson-Taylor, I More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Consejo Nacional de Ciencia y Tecnología More from this funder
University of Oxford More from this funder
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Dalton transactions (Cambridge, England : 2003) Journal website
Volume:
45
Issue:
5
Pages:
1930-1936
Publication date:
2016-02-13
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:a0b0b0f4-e23e-408b-958c-d3c59d11a93a
Source identifiers:
536549
Local pid:
pubs:536549

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