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Kinetic isotope effects in methane coupling on a reducible oxide catalyst

Abstract:

Kinetic isotope effects in methane activation on a reducible Na/MnOx/SiO2 catalyst have been investigated. The results show that there is a kinetic isotope effect for the formation of C2 products but not for the formation of COx, products. These observations conflict with kinetic measurements of the rate of formation of C2 products which appear to show that the reaction is second order with respect to the methane partial pressure. It is concluded that the rate determining step is activation o...

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Publisher copy:
10.1007/BF00764934

Authors


Publisher:
Baltzer Science Publishers, Baarn/Kluwer Academic Publishers
Journal:
Catalysis Letters
Volume:
7
Issue:
5-6
Pages:
423-430
Publication date:
1990-09-05
DOI:
EISSN:
1572-879X
ISSN:
1011-372X
URN:
uuid:a0aa4f56-608b-47f2-9200-ca9a604bbb19
Source identifiers:
180254
Local pid:
pubs:180254

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