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Structures of the metallated trihalogallate and indate ions [([n(5)-C5Me5)Fe(CO)(2)InI3](-) and [(eta 5-C5H5)Fe(CO)(2)GaI2Br](-)

Abstract:
The metallated trihalogallate and indate ions [(η 5-C 5R 5)Fe(CO)2E(X) 2X 1'] - (1: R = Me, E = In, X = X' = I; 2: R = H, E = Ga, X = I, X' = Br) isolated as the [(η 5-C 5Me 5)Fe(η 6-C 6H 5Me)] + and [Et 3NH] + salts, respectively, each features a staggered conformation about the Fe-E bond [Z centroid-Fe-E-X' = 178.9(3) (for 1) and 176.6(10)° (for 2)]. 1 represents the first crystallographically characterized half-sandwich iron complex containing a pendant trihaloindate fragment.
Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
MAIN GROUP METAL CHEMISTRY
Volume:
28
Issue:
4
Pages:
201-205
Publication date:
2005-01-01
EISSN:
2191-0219
ISSN:
0334-7575
URN:
uuid:a0967147-d952-4d6f-9213-fcb409130067
Source identifiers:
46050
Local pid:
pubs:46050
Language:
English

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