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Diffusion coefficients in ionic liquids: relationship to the viscosity.

Abstract:

The relationship between the diffusion coefficient and the viscosity has been examined in computer simulations for a number of ions diffusing in a molten salt (alkali halide) solvent. The comparison gives a measure of a hydrodynamic radius for the diffusing ions which is then compared with the bare ionic radius and a characteristic radius of the coordination complex formed by halide ions around polyvalent cations. K(+) and Cl(-) ions appear to diffuse as isolated spherical particles, whereas ...

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Publication status:
Published

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Publisher copy:
10.1021/jp046355c

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Institution:
University of Oxford
Division:
MPLS
Department:
Materials
Role:
Author
Journal:
journal of physical chemistry. B
Volume:
109
Issue:
14
Pages:
6485-6490
Publication date:
2005-04-01
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
Language:
English
Pubs id:
pubs:369728
UUID:
uuid:a07caeff-7cc6-4d83-aa6b-7ab8fe5c9d44
Local pid:
pubs:369728
Source identifiers:
369728
Deposit date:
2013-11-16

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