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Building up key segments of N-glycans in the gas phase: intrinsic structural preferences of the alpha(1,3) and alpha(1,6) dimannosides.

Abstract:

The intrinsic conformer specific vibrational spectra of two important subunits of the core pentasaccharide of N-linked glycans, the alpha(1,3) and alpha(1,6) dimannosides, have been recorded in the gas phase. Coupling these measurements with a computational exploration of their conformational landscapes has enabled their conformational assignment and has identified characteristic vibrational signatures associated with particular conformational families-including those that do or do not displa...

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Publication status:
Published

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Publisher copy:
10.1021/ja055891v

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Journal:
Journal of the American Chemical Society
Volume:
128
Issue:
6
Pages:
1976-1981
Publication date:
2006-02-05
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
URN:
uuid:9ed5d048-9ab1-4f7c-a8d4-33bd59b7f3ad
Source identifiers:
33383
Local pid:
pubs:33383

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