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Formate as a surface probe for ruthenium nanoparticles in solution 13C NMR spectroscopy

Abstract:
Formic acid adsorption on ruthemium nanoparticles of different sizes allows differentiation of differently bound formate species by solution 13C NMR spectroscopy (see picture). The chemical shifts are comparable to those of organometallic analogues, thus indicating that formate can act as a probe to distinguish surface features of metallic nanoparticles in solution with good quantification and resolution. © 2009 Wiley-VCH Verleg GmbH and Co. KgaA.

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Publisher copy:
10.1002/anie.200805240

Authors


Journal:
Angewandte Chemie - International Edition
Volume:
48
Issue:
8
Pages:
1443-1446
Publication date:
2009-02-09
DOI:
ISSN:
1433-7851
Source identifiers:
178734
Language:
English
Keywords:
Pubs id:
pubs:178734
UUID:
uuid:9e6d1d3f-99ed-4244-acdc-b7e2087827b1
Local pid:
pubs:178734
Deposit date:
2012-12-19

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