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THE WALL-JET ELECTRODE AND THE STUDY OF ELECTRODE-REACTION MECHANISMS - THE EC REACTION

Abstract:
The theory of EC reactions at a wall-jet electrode is developed using a computational procedure based on the Backwards Implicit Method. In particular, for the case of a reversible electron transfer, it is shown that the variation of the halfwave potential with solution flow rate provides a means of characterizing the EC mechanism. A working curve is presented which permits the analysis of experimental data and the deduction of the rate constant for the following chemical reaction. © 1990 Chapman and Hall Ltd.
Publication status:
Published

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Publisher copy:
10.1007/BF01019565

Authors


COMPTON, R More by this author
Publisher:
Kluwer Academic Publishers
Journal:
JOURNAL OF APPLIED ELECTROCHEMISTRY
Volume:
20
Issue:
6
Pages:
912-915
Publication date:
1990-11-05
DOI:
EISSN:
1572-8838
ISSN:
0021-891X
URN:
uuid:9e6cd1d3-c13b-4b5c-b9e0-d29a03c5b87e
Source identifiers:
43437
Local pid:
pubs:43437
Language:
English

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