THE WALL-JET ELECTRODE AND THE STUDY OF ELECTRODE-REACTION MECHANISMS - THE EC REACTION
- The theory of EC reactions at a wall-jet electrode is developed using a computational procedure based on the Backwards Implicit Method. In particular, for the case of a reversible electron transfer, it is shown that the variation of the halfwave potential with solution flow rate provides a means of characterizing the EC mechanism. A working curve is presented which permits the analysis of experimental data and the deduction of the rate constant for the following chemical reaction. © 1990 Chapman and Hall Ltd.
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