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Complex electron transfer kinetic data from convolution analysis of cyclic voltammograms. Theory and application to diamond electrodes

Abstract:

A new and versatile procedure, based on convolution analysis, for the evaluation of complex electron transfer kinetic data from cyclic voltammetnc experiments is proposed. Both the anodic and the cathodic partial reaction are analyzed independently by the use of a linearized form of the Butler-Volmer equation. It is shown that for both branches well-defined Tafel-type plots can be obtained even from quasireversible cyclic voltammograms. Processes inconsistent with Butler-Volmer kinetics can b...

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Publication status:
Published

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Authors


Neudeck, A More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
ELECTROANALYSIS
Volume:
11
Issue:
15
Pages:
1149-1154
Publication date:
1999-11-05
DOI:
EISSN:
1521-4109
ISSN:
1040-0397
URN:
uuid:9e5e4900-1836-44c3-a71d-aa189bf158b3
Source identifiers:
37211
Local pid:
pubs:37211

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