Journal article icon

Journal article

On the viability of catalytic turnover via Al-O/B-H metathesis: The reactivity of β-diketiminate aluminium hydrides towards CO2 and boranes

Abstract:

A series of β‐diketiminate stabilized aluminium hydrides of the type (Nacnac)Al(R)H has been synthesized offering variation in the auxiliary R substituent and in the Nacnac backbone. These show significant variation in the nature of the Al−H bond: electron‐donating R groups give rise to weaker (and presumably more hydridic) Al−H bonds, leading to enhanced rates of reactivity towards CO2. The resulting κ1‐formate complexes (Nacnac)Al(R){OC(O)H} have been isolated and their reactivity towards B...

Expand abstract
Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

Actions


Access Document


Files:
Publisher copy:
10.1002/chem.201802603

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Subgroup:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Subgroup:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Subgroup:
Inorganic Chemistry
Oxford college:
Lady Margaret Hall; Lady Margaret Hall
Role:
Author
ORCID:
0000-0002-7311-1663
Expand authors...
Publisher:
Wiley Publisher's website
Journal:
Chemistry Journal website
Volume:
24
Issue:
51
Pages:
13624-13635
Publication date:
2018-07-10
Acceptance date:
2018-06-19
DOI:
EISSN:
1521-3765
ISSN:
0947-6539
Pubs id:
pubs:868205
URN:
uri:9de18c76-74f9-41bd-9d14-c3eba28a84c3
UUID:
uuid:9de18c76-74f9-41bd-9d14-c3eba28a84c3
Local pid:
pubs:868205

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP