- Abstract:
-
A series of β‐diketiminate stabilized aluminium hydrides of the type (Nacnac)Al(R)H has been synthesized offering variation in the auxiliary R substituent and in the Nacnac backbone. These show significant variation in the nature of the Al−H bond: electron‐donating R groups give rise to weaker (and presumably more hydridic) Al−H bonds, leading to enhanced rates of reactivity towards CO2. The resulting κ1‐formate complexes (Nacnac)Al(R){OC(O)H} have been isolated and their reactivity towards B...
Expand abstract - Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Accepted Manuscript
- Files:
-
-
(pdf, 774.3KB)
-
- Publisher copy:
- 10.1002/chem.201802603
-
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- Publisher:
- Wiley Publisher's website
- Journal:
- Chemistry Journal website
- Volume:
- 24
- Issue:
- 51
- Pages:
- 13624-13635
- Publication date:
- 2018-07-10
- Acceptance date:
- 2018-06-19
- DOI:
- EISSN:
-
1521-3765
- ISSN:
-
0947-6539
- Pubs id:
-
pubs:868205
- URN:
-
uri:9de18c76-74f9-41bd-9d14-c3eba28a84c3
- UUID:
-
uuid:9de18c76-74f9-41bd-9d14-c3eba28a84c3
- Local pid:
- pubs:868205
- Language:
- English
- Keywords:
- Copyright holder:
- Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
- Copyright date:
- 2018
- Notes:
-
Copyright © 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim. This is the accepted manuscript version of the article. The final version is available online from Wiley at: https://doi.org/10.1002/chem.201802603
Journal article
On the viability of catalytic turnover via Al-O/B-H metathesis: The reactivity of β-diketiminate aluminium hydrides towards CO2 and boranes
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