- Abstract:
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Single-crystal to single-crystal solid/gas reactivity and catalysis starting from the precursor sigma–alkane complex [Rh(Cy2PCH2CH2PCy2)(–NBA)][BArF4] (NBA = norbornane; ArF = 3,5–(CF3)2C6H3) is reported. By adding ethene, propene and 1–butene to this precursor in solid/gas reactions the resulting alkene complexes [Rh(Cy2PCH2CH2PCy2)(alkene)x][BArF4] are formed. The ethene (x = 2) complex, [Rh(Cy2PCH2CH2PCy2)(ethene)2][BArF4]–Oct, has been characterized in the solid–state (single-crystal ...
Expand abstract - Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Publisher's version
- Files:
-
-
(pdf, 1.8MB)
-
- Publisher copy:
- 10.1039/C7SC01491K
-
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- Publisher:
- Royal Society of Chemistry Publisher's website
- Journal:
- Chemical Science Journal website
- Volume:
- 8
- Issue:
- 9
- Pages:
- 6014-6029
- Publication date:
- 2017-07-06
- Acceptance date:
- 2017-07-05
- DOI:
- EISSN:
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2041-6539
- ISSN:
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2041-6520
- Pubs id:
-
pubs:703057
- URN:
-
uri:9db53c64-31c7-43be-892c-776ea36b3ade
- UUID:
-
uuid:9db53c64-31c7-43be-892c-776ea36b3ade
- Local pid:
- pubs:703057
- Paper number:
- 9
- Copyright holder:
- Chadwick et al.
- Copyright date:
- 2017
- Notes:
- This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Journal article
Solid–state molecular organometallic chemistry. Single–crystal to single–crystal reactivity and catalysis with light hydrocarbon substrates
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SCG Chemicals Co., Ltd
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