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The total synthesis of the annonaceous acetogenin 10-hydroxyasimicin.

Abstract:
Orthogonal and modular templating is an effective basis for the preparation of the biologically active annonaceous acetogenin 10-hydroxyasimicin (1). The versatile tartrate-derived 2,3-butanediacetal building block together with a highly diastereoselective hetero-Diels-Alder approach to the butenolide unit were usefully employed in this novel synthetic route.
Publication status:
Published

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Publisher copy:
10.1002/anie.200462264

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Role:
Author
Journal:
Angewandte Chemie (International ed. in English)
Volume:
44
Issue:
4
Pages:
580-584
Publication date:
2005-01-05
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
URN:
uuid:9da7f136-6347-4ae4-a155-02d280ad8cdf
Source identifiers:
52062
Local pid:
pubs:52062
Language:
English
Keywords:

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