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[Cu(HF2)2(pyz)]n: A rectangular antiferromagnetic lattice with a spin exchange path made up of two different FHF- bridges

Abstract:
The two-dimensional antiferromagnet [Cu(HF2)2(pyz)] n (pyz=pyrazine) has a rectangular lattice (see picture) displaying two types of FHF- bridging modes. The spin exchange through Cu-(FHF)2-Cu is about 90% stronger than through Cu-pyz-Cu, and the 1,1-coordinated FHF-, which is close in nature to F - ⋯ HF, is largely responsible for the exchange. C black, Cu red, F green, H cyan. © 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.

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Publisher copy:
10.1002/anie.201006653

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Journal:
Angewandte Chemie - International Edition
Volume:
50
Issue:
7
Pages:
1573-1576
Publication date:
2011-02-11
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
URN:
uuid:9cc1d4e3-2072-43e9-8fff-741928f8ee34
Source identifiers:
120536
Local pid:
pubs:120536

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