- Abstract:
- The elucidation of the structure of the cytotoxic marine sponge alkaloid pyrinodemin A by synthesis is described. Based on the 13C NMR spectra of three double bond positional isomers and the natural product, it is concluded the C14′-C15′ isomer best represents the true structure of pyrinodemin A. In addition, the structural assignment of pyrinodemin C is evaluated. © 2004 Elsevier Ltd. All rights reserved.
- Publication status:
- Published
- Publisher copy:
- 10.1016/j.tet.2004.11.051
-
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- Journal:
- TETRAHEDRON
- Volume:
- 61
- Issue:
- 5
- Pages:
- 1127-1140
- Publication date:
- 2005-01-31
- DOI:
- ISSN:
-
0040-4020
- URN:
-
uuid:9cb6929a-e707-410c-a17c-ee1992a57e73
- Source identifiers:
-
117895
- Local pid:
- pubs:117895
- Language:
- English
- Keywords:
- Copyright date:
- 2005
Journal article
On the synthesis of pyrinodemin A. Part 1: The location of the olefin
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