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A kinetic study of the intercalation of lithium salts into Al(OH)3.

Abstract:

The intercalation of five lithium salts into the gibbsite and bayerite polymorphs of Al(OH)3 has been studied using in situ energy-dispersive X-ray diffraction. The kinetics and mechanisms of the reactions have been modeled using the Avrami-Erofe'ev model. The kinetic data suggest that the reaction mechanisms are predominantly nucleation controlled, although the intercalation of LiNO3 into bayerite and of Li2SO4 into gibbsite proceed via two-stage mechanisms, one part of which is diffusion co...

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Publication status:
Published

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Publisher copy:
10.1021/jp057130k

Authors


Williams, GR More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
The journal of physical chemistry. B
Volume:
110
Issue:
22
Pages:
10619-10629
Publication date:
2006-06-05
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
URN:
uuid:9c4bc503-e962-4bbc-9dbd-b06c7ea26927
Source identifiers:
51297
Local pid:
pubs:51297
Language:
English

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