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TIN PHOSPHORUS NUCLEAR-SPIN COUPLING IN OCTAHEDRAL COMPLEXES OF TIN(IV)

Abstract:
Heteronuclear magnetic multiple resonance experiments are used to show that the large values of 1J(119Sn31P) found in tertiary phosphine complexes of tin tetrahalides are negative [corresponding to a positive 1K(SnP)], suggesting that the mean excitation energy approximation can provide a valid description of the Fermi contact contribution to this spin coupling interaction, in contrast to the situation for other types of SnP interaction over one bond. © 1989.
Publication status:
Published

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Journal:
POLYHEDRON
Volume:
8
Issue:
16
Pages:
2047-2050
Publication date:
1989-01-01
DOI:
ISSN:
0277-5387
URN:
uuid:9c486fd1-44ea-4464-8aaa-2c477ed4ca72
Source identifiers:
115962
Local pid:
pubs:115962
Language:
English

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