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THE STRUCTURAL AND MAGNETIC-PROPERTIES OF SRMNO3 - A REINVESTIGATION

Abstract:
Neutron diffraction and Mössbauer spectroscopy have revealed that the phase 4H-SrMnO3 is paramagnetic at 290 K, contrary to earlier reports. Mössbauer spectroscopy on57Fe-doped samples has revealed antiferromagnetic ordering withTN = 278 ± 5K. The susceptibility maximum at ∼350 K is thought to represent only short-range coupling between Mn4+ ions in the Mn2O9 pairs of face-sharing octahedra in the structure. © 1988 Academic Press, Inc. All rights reserved.
Publication status:
Published

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Journal:
JOURNAL OF SOLID STATE CHEMISTRY
Volume:
74
Issue:
1
Pages:
60-66
Publication date:
1988-05-05
DOI:
EISSN:
1095-726X
ISSN:
0022-4596
URN:
uuid:9c29b363-7008-4c78-acef-f533b9eef15a
Source identifiers:
46485
Local pid:
pubs:46485
Language:
English

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