- Abstract:
-
A large and diverse library of trans-A2B2 and A 2BC-porphyrins possessing two arylethynyl substituents at the meso positions has been efficiently synthesized and tested for their two-photon absorption (2PA) behavior. All compounds fall into three general types A-π-A, D-π-D or D-π-A, where A is an electron-acceptor and D is an electron-donor moiety. These porphyrins contain two polyalkoxyaryl substituents, resulting in very low melting points (typically 110-125 °C) and superb solubility in non...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1039/c3tc00594a
-
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- Journal:
- JOURNAL OF MATERIALS CHEMISTRY C
- Volume:
- 1
- Issue:
- 10
- Pages:
- 2044-2053
- Publication date:
- 2013-01-01
- DOI:
- EISSN:
-
2050-7526
- ISSN:
-
2050-7526
- URN:
-
uuid:9c16ba2d-ac1b-49bd-bd9a-4464027c414e
- Source identifiers:
-
388151
- Local pid:
- pubs:388151
- Copyright date:
- 2013
Journal article
Synthesis and linear and nonlinear optical properties of low-melting pi-extended porphyrins
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