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Synthesis and linear and nonlinear optical properties of low-melting pi-extended porphyrins

Abstract:

A large and diverse library of trans-A2B2 and A 2BC-porphyrins possessing two arylethynyl substituents at the meso positions has been efficiently synthesized and tested for their two-photon absorption (2PA) behavior. All compounds fall into three general types A-π-A, D-π-D or D-π-A, where A is an electron-acceptor and D is an electron-donor moiety. These porphyrins contain two polyalkoxyaryl substituents, resulting in very low melting points (typically 110-125 °C) and superb solubility in non...

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Publication status:
Published

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Publisher copy:
10.1039/c3tc00594a

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Journal:
JOURNAL OF MATERIALS CHEMISTRY C
Volume:
1
Issue:
10
Pages:
2044-2053
Publication date:
2013-01-01
DOI:
EISSN:
2050-7526
ISSN:
2050-7526
URN:
uuid:9c16ba2d-ac1b-49bd-bd9a-4464027c414e
Source identifiers:
388151
Local pid:
pubs:388151

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