Journal article icon

Journal article

Steady state voltammetry at non-uniformly accessible electrodes: a study of Tafel plots for microdisc and tubular flow electrodes in the reversible and irreversible limits of electron transfer.

Abstract:
Steady state concentration profiles are obtained via numerical solution for an electron transfer at the microdisc and tubular flow electrodes. The non-uniform flux profiles over the electrode surfaces and their effect on the voltammetric waveshape are discussed. An approach is suggested for the most appropriate way to estimate the charge transfer coefficient from an experimental voltammogram of an irreversible electron transfer.
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1039/b615417d

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
Physical chemistry chemical physics : PCCP
Volume:
9
Issue:
7
Pages:
862-870
Publication date:
2007-02-01
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
Source identifiers:
33752
Language:
English
Pubs id:
pubs:33752
UUID:
uuid:9bb02570-eaf0-4271-85cf-b638240251ed
Local pid:
pubs:33752
Deposit date:
2012-12-19

Terms of use


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP