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Highly efficient phosphodiester hydrolysis promoted by a dinuclear copper(II) complex.

Abstract:

The interaction of Cu(II) with the ligand tdci (1,3,5-trideoxy-1,3,5-tris(dimethylamino)-cis-inositol) was studied both in the solid state and in solution. The complexes that were formed were also tested for phosphoesterase activity. The pentanuclear complex [Cu(5)(tdciH(-2))(tdci)(2)(OH)(2)(NO(3))(2)](NO(3))(4).6H(2)O consists of two dinuclear units and one trinuclear unit, having two shared copper(II) ions. The metal centers within the pentanuclear structure have three distinct coordination...

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Publication status:
Published

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Publisher copy:
10.1021/ic0005902

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Journal:
Inorganic chemistry
Volume:
40
Issue:
19
Pages:
4918-4927
Publication date:
2001-09-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:9b2f54a4-da4f-4b22-92a0-8aabdaeb1718
Source identifiers:
326057
Local pid:
pubs:326057

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