- Abstract:
-
Radical anions of 1-bromo-4-nitrobenzene (p-BrC6H4NO2) are shown to be reactive in the room temperature ionic liquid N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, ([C4mPyrr][NTf2]), by means of voltammetric measurements. In particular, they are shown to react via a DISP type mechanism such that the electrolysis of p-BrC6H4NO2 occurs consuming between one and two electrons per reactant molecule, leading to the formation of the nitrobenzene radical anion and bromide ions. Thi...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1039/c3cp51004b
-
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- Journal:
- Physical chemistry chemical physics : PCCP
- Volume:
- 15
- Issue:
- 17
- Pages:
- 6382-6389
- Publication date:
- 2013-05-05
- DOI:
- EISSN:
-
1463-9084
- ISSN:
-
1463-9076
- URN:
-
uuid:9aa7c88f-0cfa-49ec-9c1f-2690c572ce0e
- Source identifiers:
-
390817
- Local pid:
- pubs:390817
- Language:
- English
- Keywords:
- Copyright date:
- 2013
Journal article
Changed reactivity of the 1-bromo-4-nitrobenzene radical anion in a room temperature ionic liquid.
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