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ENANTIOSPECIFIC SYNTHESIS OF SWAINSONINE, (1S, 2R, 8R, 8AR)-1,2,8-TRIHYDROXYOCTAHYDROINDOLIZINE, FROM D-MANNOSE

Abstract:
An enantiospecific synthesis of swainsonine from D-mannose is described; the heterocyclic rings of swainsonine are constructed by two intramolecular reductive aminations caused by the catalytic hydrogenation of an azidoaldehyde with 5 equivalents of hydrogen. © 1984.
Publication status:
Published

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Journal:
TETRAHEDRON LETTERS
Volume:
25
Issue:
17
Pages:
1853-1856
Publication date:
1984-01-01
DOI:
ISSN:
0040-4039
URN:
uuid:9a8f9f21-1c1e-4ae6-a9be-a8cf8221cb56
Source identifiers:
42325
Local pid:
pubs:42325
Language:
English

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