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A family of scandium and yttrium tris((trimethylsilyl)methyl) complexes with neutral N-3 donor ligands

Abstract:

The synthesis and reactivity scandium and yttrium tris((trimethylsilyl)methyl) complexes family with neutral N3 donor ligands were studied. The effective synthetic routes to the first group 3 organometallic and coordination compounds containing the tris(pyrazolyl) methane and triazacyclohexane ligands were described. All manipulations were carried out under standard Schlenk line or drybox techniques under an atmosphere of argon or of dinitrogen. The stoitiometric and catalytic chemistry of ca...

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Publication status:
Published

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Publisher copy:
10.1021/om050209r

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Journal:
ORGANOMETALLICS
Volume:
24
Issue:
13
Pages:
3136-3148
Publication date:
2005-06-20
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
URN:
uuid:9a7f1948-ad9b-4f18-bbfe-c395aae9d1b4
Source identifiers:
51313
Local pid:
pubs:51313
Language:
English

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