Journal article icon

Journal article

A NEW CHROMOPHORIC AND REDOX-RESPONSIVE IONOPHORE CONTAINING A TRICYANOVINYL MOIETY

Abstract:
The treatment of tetracyanoethylene (1) with N-phenylaza-15-crown-5 (3) gives a new chromophoric and redox-responsive ionophore, 5, containing a tricyanovinyl redox-active moiety. The electronic absorption spectrum of 5 exhibits hypochromic shifts on binding alkali and alkaline earth metal cations. Cyclic voltammetric electrochemical investigations reveal 5 to electrochemically recognize Na+ and K+ guest cations resulting in shifts of the tricyanovinyl reduction wave to more anodic potentials. © 1990.
Publication status:
Published

Actions


Access Document


Authors


SIKANYIKA, H More by this author
Journal:
POLYHEDRON
Volume:
9
Issue:
14
Pages:
1747-1749
Publication date:
1990
DOI:
ISSN:
0277-5387
URN:
uuid:9a1a5d42-4edc-4bac-91f0-2e026eabeb48
Source identifiers:
46084
Local pid:
pubs:46084
Language:
English

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP