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[Rh{NC5H3-2,6-((CH2PBu2)-Bu-t)(2)}(PCY3)][BAr4F]: A Latent Low-Coordinate Rhodium(I) PNP Pincer Compound

Abstract:
An expedient new route to the cationic [(PNPtBu)Rh(L)] + metal fragments (PNPtBu = κ3-NC 5H3-2,6-(CH2P tBu2) 2; L = CO, acetone, ethene, MeCN, N2) by the synthesis of, then substitution of PCy3 in, [(PNPtBu)Rh(PCy 3)][BArF4] is reported. This synthetic route also allows for the synthesis of the new dihydrogen complex [(PNP tBu)Rh(H2)][BArF4]. [(PNP R)Rh(PCy3)][BArF4] (R= Ph, Cy, Mes) are also reported, in which the PCy3 ligand is more tightly bound to the metal center. © 2011 American Chemical Society.
Publication status:
Published

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Publisher copy:
10.1021/om2004964

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
ORGANOMETALLICS
Volume:
30
Issue:
16
Pages:
4466-4469
Publication date:
2011-08-22
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
URN:
uuid:9a010816-c17f-4871-ad8f-269bf2135095
Source identifiers:
175451
Local pid:
pubs:175451
Language:
English

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