Journal article icon

Journal article

Voltammetric monitoring of photochemical reactions: The photosubstitution of group VIA hexacarbonyls

Abstract:
Voltammetry at an irradiated platinum channel electrode is used to monitor photosubstitution reactions of the Group VIA hexacarbonyls, M(CO)6 (M = Cr,Mo,W), in acetonitrile solution, in which up to three CO ligands are replaced by solvent molecules. It is shown that this methodological approach can be used to suggest reaction mechanisms and to quantify rates of photoreactions, so giving estimates of quantum yields.
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1002/elan.1140060109

Authors


More by this author
Institution:
University of Oxford
More by this author
Institution:
University of Oxford
More by this author
Institution:
University of Oxford
More by this author
Institution:
University of Oxford
Journal:
Electroanalysis
Volume:
6
Issue:
1
Pages:
45-50
Publication date:
1994-01-05
DOI:
EISSN:
1521-4109
ISSN:
1040-0397
URN:
uuid:99bab93a-370b-4349-97d0-b477c3565338
Source identifiers:
44335
Local pid:
pubs:44335

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP